Free charge localization and effective dielectric permittivity in oxides

Polarons, free charge localisation and effective dielectric permittivity in oxides

This review will deal with several types of free charge localisation in oxides and their consequences on the effective dielectric spectra of such materials. The first one is the polaronic localisation at the unit cell scale on residual impurities in ferroelectric networks. The second one is the collective localisation of free charge at macroscopic interfaces like surfaces, electrodes and grain ...

Charge localization increases chemical expansion in cerium-based oxides.

In this work, we demonstrate the mechanism by which electronic charge localization increases the chemical expansion coefficient in two model systems, CeO(2-δ) and BaCeO(3-δ). Using Density Functional Theory calculations, we predict that this coefficient is increased by more than 70% when charge is fully localized, consistent with the observation that materials with a smaller degree of charge lo...

Dielectric Permittivity and Electric Modulus in Bi2Ti4O11

Charge localization instability in a highly deformable dielectric elastomer

This paper shows that a highly deformable capacitor made of a soft dielectric and two conformal electrodes can switch between two states discontinuously, by a first-order transition, as the total charge varies gradually. When the total charge is small, it spreads evenly over the area of the capacitor, and the capacitor deforms homogeneously. When the total charge is large, it localizes in a sma...

Analysis of nonlocal effective permittivity and permeability in symmetric metal– dielectric multilayer metamaterials

A generalized nonlocal effective medium theory is derived based on the transfer-matrix method to determine the nonlocal effective permittivity and permeability for the symmetric and periodic metal–dielectric multilayer metamaterials, with respect to both transverse-electric and transversemagnetic polarized light at arbitrary angle of incidence. The nonlocal effective permittivity and permeabili...